דווקאDAV-kah[ˈdavka]
precisely this one, and often precisely to annoy
Closest in English: spite, spitefully, contrariness. None of them covers it.
It came from an Aramaic word for exactness and grew a personality on the way. Davka marks the option chosen on purpose, usually the awkward one: the child who eats everything on the plate except the thing you cooked. One word does duty for precisely and for out of sheer contrariness.
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Harder than most words so far.